Product ID:REFRIGERANT 114 DICHLOROTETRAFLUOROETHANE
MSDS Date:09/01/1991
FSC:6810
NIIN:00-782-6512
MSDS Number: BHHPL

Emergency Phone: 609-455-4555(CHEMTREC 800-424-9300)

Info Phone: 609-455-4555

Preparer: T. NAPRAVA

Cage: 4J994

Telephone: 800-262-0012/215-698-6620

Cage: 4J994

1,2-DICHLOROTETRAFLUOROETHANE

CAS: 76-14-2

RTECS: KI1101000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9394

LD50 LC50 Mixture:INHALATION LC50 (RAT)=720,000 PPM/30 MIN
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HUMAN HEALTH EFFECTS BY
INHALATION, INGESTION, SKIN OR EYE CONTACT MAY INCLUDE: NERVOUS
SYSTEM DEPRESSION; ALTER HEART ELECTRICAL ACTIVITY; ABNORMAL LIVER
FUNCTION; DEATH. INTENTIONAL MISUSE CA N BE FATAL. CHRONIC: NONE
SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NO INGREDIENTS OF A CONCENTRATION OF
0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, DROWSINESS, NAUSEA,
TINGLING OR NUMBNESS OF THE EXTREMITIES, SENSES OF FULLNESS IN THE
HEAD, SENSE OF WARMTH, STUPOR OR DULLNESS, LETHARGY AND DRUNKENESS.
VERY HIGH CONCENTRATIONS MAY LEAD TO UNCONSCIOUSNESS OR EVEN DEATH
IN CONFINED OR POORLY VENTILATED AREAS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM MAY
HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE
EXPOSURES.

First Aid:INGESTED-CALL A DOCTOR.DO NOT INDUCE VOMITING.INHALED-REMOVE
TO FRESH AIR.IF NOT BREATHING,GIVE ARTIFICIAL RESPIRATION.IF
BREATHING DIFFICULT,GIVE OXYGEN.CALL A DOCTOR.SKIN-FLUSH WITH LOTS
OF WATER.GE T MEDICAL ATTENTION IF IRRITATION
PERSISTS.EYES-IMMEDIATELY FLUSH WITH LOTS OF WATER FOR AT LEAST 15
MINUTES.CALL A DOCTOR.NOTE:DO NOT GIVE CATECHOLAMINE DRUGS DUE TO
CARDIAC RHYTHM DISTURBANCES.

Flash Point Method:TOC
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS (SCBA) MAY
BE REQUIRED IF CYLINDERS RUPTURE OR RELEASE UNDER FIRE CONDITIONS.
USE WATER FOG TO COOL FIRE EXPOSED CYLINDERS.
Unusual Fire/Explosion Hazard:CYLINDERS ARE EQUIPPED WITH PRESSURE AND
TEMPERATURE RELIEF DEVICES BUT STILL MAY RUPTURE UNDER FIRE
CONDITIONS. DECOMPOSITION MAY OCCUR.

Spill Release Procedures:VENTILATE AREA, ESPECIALLY LOW PLACES WHERE
HEAVY VAPORS MIGHT COLLECT. USE SELF-CONTAINED BREATHING APPARATUS
IN CASE OF LARGE SPILLS. COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS ON REPORTING RE LEASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
DLA-HMIS: STORE IN A COOL, DRY PLACE AWAY FROM INCOMPATIBLE
MATERIALS.
Other Precautions:EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. DO
NOT BREATH DUST, VAPOR, MIST OR GAS. DO NOT GET IN EYES OR ON SKIN.

Respiratory Protection:NONE NORMALLY REQUIRED. DLA-HMIS: IF ENGINEERING
CONTROLS FAIL OR NON-ROUTINE USE OR EMERGENCY OCCURS; USE
NIOSH/MSHA APPROVED SUPPLIED AIR RESPIRATOR OR SCBA, AS REQUIRED.
USE IAW 29 CFR 1910.134 AND MANUFACTURER'S RECOMMENDATION.
Ventilation:NORMAL VENTILATION FOR STD MANUFACTURING PROCEDURES IS
GENERALLY ADEQUATE.USE LOCAL EXHAUST IF LARGE AMOUNTS RELEASED.
Protective Gloves:BUTYL
Eye Protection:CHEMICAL SAFETY GOGGLES & FACE SHIELD.
Other Protective Equipment:NONE NORMALLY REQUIRED. DLA-HMIS: APRON AND
WORK CLOTHING TO MINIMIZE EXPOSURE.EYE WASH STATION & SAFETY SHOWER
RECOMMED
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST.
Supplemental Safety and Health
THIS NSN REPRESENTS REPLACEMENT PRODUCT. EMPTY CYLINDER
NSN=8120-001781598; FILLED CYLINDER NSN=6830-002904379.

HCC:G3
Boiling Pt:B.P. Text:39.0F,3.9C
Vapor Pres:1572 MM HG
Vapor Density:0.98
Evaporation Rate & Reference:>1 (CCL4=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS, LIQUEFIED GAS WITH SLIGHT ETHEREAL
ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS - POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:HYDROGEN FLUORIDE, HYDROGEN CHLORIDE,
AND POSSIBLE CARBONYL HALIDES.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS.REMOVE TO PERMITTED WASTE DISPOSAL FACILITY.SARA TITLE
III INFO: EHS (40CFR355)-NONE; CERCLA (40CFR302.4)-NONE; SARA
311/312-IMMEDIATE;313(40CFR372)-DI
CHLOROTETRAFLUOROETHANE,CAS#76-14-2,100%

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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.